Heat Exchanger Fouling and Rubby Formation
Heat exchanger fouling in methanol plants can be a symptom of a deeper problem inside the Auto-Thermal Reformer (ATR): Ruby (or Rubby) Formation. This phenomenon occurs when impurities and hot spots weaken the catalyst support, releasing silica particles that deposit on exchanger tubes and reduce thermal efficiency. Several mitigation approaches are applied in industry — among them Steam Washing, impurity control, optimized ATR operation, and improved catalyst formulations — to limit fouling and maintain reliable plant performance.

